NOS Buick brand Piston Ring Set. Based on the part number, I believe this fits '59-'66 nailheads.
The specific part number does not appear in my chassis parts book, but is similar to part nubmers from '59-'66 oversize sets.
Inside part numbers are BT-10, RBT-10 and CS-50. Sounds like .10 oversize to me, but that's just a guess.
Rings are slightly tarnished, but should clean up well.
Great original box would make an excellent display piece.